Publications
2022-present
141. B. J. Neyhouse, N. A. Price, F. R. Brushett, A Computationally Efficient, Zero-Dimensional Stack Model for Simulating Redox Flow Battery Performance. Journal of the Electrochemical Society, 2025. DOI: 10.1149/1945-7111/ad9e30
140. K. M. Ripley, F. R. Brushett, Modeling and Comparative Analysis of CO2 Absorption Columns in Electrochemical and Thermochemical Carbon Capture Systems. Ind. Eng. Chem. Res., 2024. DOI: 10.1021/acs.iecr.4c01523
139. L. E. Clarke, K. M. Ripley, F. R. Brushett, Insights into Energetic Penalties in Electrochemical CO2 Separation Systems. Ind. Eng. Chem. Res., 2024. DOI: 10.1021/acs.iecr.4c01763
138. B.J. Neyhouse, F. R. Brushett, A Spreadsheet-Based Redox Flow Battery Cell Cycling Model Enabled by Closed-Form Approximations. Journal of The Electrochemical Society, 2024. DOI: 10.1149/1945-7111/ad5d68
137. C.T. Mallia, F. R. Brushett, Phenomenological Observations of Quinone-Mediated Zinc Oxidation in an Alkaline Environment. Chem. Commun. 2024. DOI: 10.1039.D4CC02746A
136. R. Wang, K. Yang, C. Wong, H. Aguirre-Villegas, R. Larson, F. R. Brushett, M. Qin, and S. Jin, Electrochemical ammonia recovery and co-production of chemicals from manure wastewater, Nature Sustainability, 2024, 7, 2, 179–190. DOI: 10.1038/s41893-023-01252-z
135. L. Kong, Y. Zhu, P. J. Williams, M. Kabbani, F. R. Brushett, and J. L. M. Rupp, Insights into Li+ storage mechanisms, kinetics, and reversibility of defect-engineered and functionalized multiwalled carbon nanotubes for enhanced energy storage, Journal of Materials Chemistry A, 2024, 12, 4299-4311. DOI: 10.1039/D3TA07362A
134. K. M Tenny, Y. -M. Chiang, and F. R. Brushett, Electrochemical Residence Time Distribution as a Diagnostic Tool for Redox Flow Batteries, Journal of The Electrochemical Society, 2023, 170, 12, 120518. DOI: 10.1149/1945-7111/ad0807
133. A. H. Quinn, K. M. Ripley, N. J. Matteucci, B. J. Neyhouse, C. A. O. Brown, W. P. Woltmann, and F. R. Brushett, Elucidating the effects of temperature on nonaqueous redox flow cell cycling performance, Journal of The Electrochemical Society, 2023, 170, 12, 120520. DOI: 10.1149/1945-7111/ad0e44
132. N .J. Matteucci, C. T. Mallia, B. J. Neyhouse, M. V. Majji, and F. R. Brushett, Toward Electrochemical Design Principles of Redox-Mediated Flow Batteries, Current Opinion in Electrochemistry, 2023, 42, 101380. DOI: 10.1016/j.coelec.2023.101380
131. A. M. Fenton, Jr., B. J. Neyhouse, K. M. Tenny, Y. Chiang, F. R. Brushett, An automated and lightweight framework for electrolyte diagnostics using quantitative microelectrode voltammetry, Journal of Electroanalytical Chemistry, 2023, Volume 947, 117689
130. C. T. Wan, R. M. Darling, Y. Chiang, F. R. Brushett, Modeling Nanoscale Ohmics in Carbon Supports of Fuel Cell Cathodes, Journal of the Electrochemical Society, 2023. DOI: 10.1149/1945-7111/acd4ef
129. W. Gao, J. Drake, F. R. Brushett, Modeling the Impact of Electrolyte Flow on Heat Management in a Li-Ion Convection Cell, Journal of the Electrochemical Society, 2023. 170 (9), DOI: 10.1149/1945-7111/aceab4
128. B. J. Neyhouse, R. M. Darling, J. D. Saraidaridis, F. R. Brushett, A method for quantifying crossover in redox flow cells through compositionally unbalanced symmetric cell cycling, Journal of the Electrochemical Society, 2023. 170 (8), 080514. DOI: 10.1149/1945-7111/ace938
127. A. M. Zito, L. E. Clarke, J. M. Barlow, D. Bim, Z. Zhang, K. Ripley, C. J. Li, A. Kummeth, M. E. Leonard, A. N. Alexandrova, F. R. Brushett, and J. Y. Yang, Electrochemical Carbon Dioxide Capture and Concentration, Chem. Rev. 2023, 123, 13, 8069–8098. DOI: https://doi.org/10.1021/acs.chemrev.2c00681
126. T. A. Weiss, G. Fan, B. J. Neyhouse, E. B. Moore, A. L. Furst, F. R. Brushett, Characterizing the Impact of Oligomerization on Redox Flow Cell Performance, Batteries and Supercaps, Chemistry Europe, 2023. 6 (8), DOI: https://doi.org/10.1002/batt.202300034
125. M. V. Majji, B. J. Neyhouse, N.J. Matteucci, K. R. Lennon, C. T. Mallia, A. M. Fenton, Jr., J. W. Swan, and F. R. Brushett, Modeling Electrochemical and Rheological Characteristics of Suspension-Based Electrodes for Redox Flow Cells, Journal of The Electrochemical Society, 2023, 170 050532. DOI: 10.1149/1945-7111/accb74
124. A. M. Fenton, Jr., F. R. Brushett, Leveraging graphical models to enhance in situ analyte identification via multiple voltammetric techniques, Journal of Electroanalytical Chemistry, 2023, Volume 936, 117299. DOI: https://doi.org/10.1016/j.jelechem.2023.117299
123. K. E. Rodby, R. L. Jaffe, E. A. Olivetti, F. R. Brushett, Materials availability and supply chain considerations for vanadium in grid-scale redox flow batteries, Journal of Power Sources, 2023, Volume 560, 232605. DOI: https://doi.org/10.1016/j.jpowsour.2022.232605
122. J. J. Patil, C. T. Wan, S. Gong, Y. Chiang, F. R. Brushett, and J. C. Grossman, Bayesian-Optimization-Assisted Laser Reduction of Poly(acrylonitrile) for Electrochemical Applications, ACS Nano, 2023. 17, 5, 4999–5013. DOI: https://doi.org/10.1021/acsnano.2c12663
121. C. T. Wan, A. Ismail, A. H. Quinn, Y. Chiang, F. R. Brushett, Synthesis and Characterization of Dense Carbon Films as Model Surfaces to Estimate Electron Transfer Kinetics on Redox Flow Battery Electrodes, Langmuir, 2023. 39, 3, 1198–1214, DOI: https://doi.org/10.1021/acs.langmuir.2c03003
120. A. P. Kaur, B. J. Neyhouse, I. A. Shkrob, Y. Wang, N. H. Attanayake, R. K. Jha, Q. Wu, L. Zhang, R. H. Ewoldt, F. R. Brushett, S. A. Odom, Concentration-dependent cycling of phenothiazine-based electrolytes in nonaqueous redox flow cells, Chemistry an Asian Journal, 2023. 18(5), e202201171. DOI: https://doi.org/10.1002/asia.202201171
119. C. T. Wan, K. E. Rodby, M. L. Perry, Y. Chiang and F. R. Brushett, Hydrogen evolution mitigation in iron-chromium redox flow batteries via electrochemical purification of the electrolyte, Journal of Power Sources, 2023. 54, 232248, DOI: 10.1016/j.jpowsour.2022.232248
118. A. M. Fenton, Jr., Y. A. Gandomi, C. T. Mallia, B. J. Neyhouse, A. Kpeglo, W. E. Exson, C. T. Wan, and F. R. Brushett, Toward a Mechanically Rechargeable Solid Fuel Flow Battery Based on Earth-Abundant Materials, ACS Omega, 2022. DOI: 10.1021/acsomega.2c05798
117. J. M. Barlow, L. E. Clarke, Z. Zhang, D. Bím, K. M. Ripley, A. Zito, F. R. Brushett, A. N. Alexandrova, and J. Y. Yang, Molecular Design of Redox Carriers for Electrochemical CO2 Capture and Concentration, Chemical Society Reviews, 2022. DOI: 10.1039/D2CS00367H
116. B. J. Neyhouse, J. Lee, F. R. Brushett, Connecting material properties and redox flow cell cycling performance through zero-dimensional models, Journal of The Electrochemical Society, 2022. 169(9), 090503 – DOI: 10.1149/1945-7111/ac86aa
115. A. M. Fenton Jr., R. Kant Jha, B. J. Neyhouse, A. P. Kaur, D. A. Dailey, S. A. Odom, F. R. Brushett, On the challenges of materials and electrochemical characterization of concentrated electrolytes for redox flow batteries, Journal of Materials Chemistry A, 2022. DOI: 10.1039/d2ta00690a
In memory of Prof. Susan A. Odom
114. M. S. Pan, L. Su, , S. L. Eiler, L. W. Jing, A. F. Badel, Z. Li, F. R. Brushett, and Y. Chiang, Electrochemical Stability and Reversibility of Aqueous Polysulfide Electrodes Cycled Beyond the Solubility Limit, Journal of The Electrochemical Society, 2022. DOI: 10.1149/1945-7111/ac7669
113. K. M. Tenny, K.V. Greco, M. V. Heijden, T. Pini, A. Mularczyk, A. Vasile, J. Eller, A. Forner-Cuenca, Y. Chiang, and F. R. Brushett, A Comparative Study of Compressive Effects on the Morphology and Performance of Carbon Paper and Cloth Electrodes in Redox Flow Batteries, Energy Technology, 2022. DOI: 10.1002/ente.202101162
112. L.E. Clarke, M.E. Leonard, T.A. Hatton, and F. R. Brushett, Thermodynamic Modeling of CO2 Separation Systems with Soluble, Redox-Active Capture Species, Industrial & Engineering Chemistry Research, 2022. DOI: 10.1021/acs.iecr.1c04185
111. R. R. Jacquemond, C. T. Wan, Y. Chiang, Z. Borneman, F. R. Brushett, K. Nijmeijer, and A. Forner-Cuenca, Microstructural engineering of high-power redox flow battery electrodes via non-solvent induced phase separation, Cell Reports Physical Science, 2022. DOI: 10.1016/j.xcrp.2022.100943
110. A. Alazmi, C. T. Wan, P. M. Costa, and F. R. Brushett, Exploration of Reduced Graphene Oxide Microparticles as Electrocatalytic Materials in Vanadium Redox Flow Batteries, Journal of Energy Storage, 2022, 50,104192
109. M. L. Perry, K. E. Rodby, and F. R. Brushett, Untapped Potential: The Need and Opportunity for High-Voltage Aqueous Redox Flow Batteries, ACS Energy Letters, 2022. 7, 659-667
108. B. A. Simon, A. Gayon-Lombardo, C. A. Pino-Muñoz, C. E. Wood, K. M. Tenny, K. V. Greco, S. J. Cooper, A. Forner-Cuenca, F. R. Brushett, A. R. Kucernak, and N. P. Brandon, Combining Electrochemical and Imaging Analyses to Understand the Effect of Electrode Microstructure and Electrolyte Properties on Redox Flow Batteries, Applied Energy, 2022.
306 (Part B), 117678
107. A. M. Fenton Jr. and F. R. Brushett, Using Voltammetry Augmented with Physics-based Modeling and Bayesian Hypothesis Testing to Identify Analytes in Electrolyte Solutions, Journal of Electroanalytical Chemistry, 2022. 904, 115751
106. C. T. Wan, K. V. Greco, A. Alazmi, R. M. Darling, Y.-M. Chiang, and F. R. Brushett, Methods—A Potential–Dependent Thiele Modulus to Quantify the Effectiveness of Porous Electrocatalysts, Journal of the Electrochemical Society, 2021. 168(12), 123503
105. Z. Cheng, K. M. Tenny, A. Pizzolato, A. Forner-Cuenca, V. Verda, Y.-M. Chiang, F. R. Brushett, and R. Behrou, A Generalized Reduced Fluid Dynamic Model for Flow Fields and Electrodes in Redox Flow Batteries, AIChE Journal, 2021. DOI: 10.1002/aic.17540
104. B. J. Neyhouse, K. M. Tenny, Y.-M. Chiang, and F. R. Brushett, Microelectrode-Based Sensor for Measuring Operando Active Species Concentrations in Redox Flow Cells, ACS Applied Energy Materials, 2021. 4(12), 13830-13840
103. K. V. Greco, J. K. Bonesteel, N. Chanut, C. T. Wan, Y.-M. Chiang, and F. R. Brushett, Limited Accessibility to Surface Area Generated by Thermal Pretreatment of Electrodes Reduces Its Impact on Redox Flow Battery Performance, ACS Applied Energy Materials, 2021. 4(12), 13516-13527
102. Y. Ashraf Gandomi, I. V. Krasnikova, N. O. Akhmetov, N. A. Ovsyannikov, M. A. Pogosova, N. J. Matteucci, C. T. Mallia, B. J. Neyhouse, A. M. Fenton Jr., F. R. Brushett, and K. J. Stevenson, Synthesis and Characterization of Lithium-Conducting Composite Polymer–Ceramic Membranes for Use in Nonaqueous Redox Flow Batteries, ACS Applied Materials & Interfaces, 2021. 13(45), 53746-53757
101. B. J. Neyhouse and F. R. Brushett, From the Synthesis Vial to the Full Cell: Electrochemical Methods for Characterizing Active Materials for Redox Flow Batteries, Encyclopedia of Energy Storage, 2022. 2, 453-465
2018-2021
100. K. E. Rodby, M. L. Perry, and F. R. Brushett, Assessing Capacity Loss Remediation Methods for Asymmetric Redox Flow Battery Chemistries Using Levelized Cost of Storage, Journal of Power Sources, 2021. 506, 230085
99. K. M. Tenny, R. D. Braatz, Y.-M. Chiang, and F. R. Brushett, Leveraging Neural Networks and Genetic Algorithms to Refine Electrode Properties in Redox Flow Batteries, Journal of the Electrochemical Society, 2021. 168(5), 050547
98. Z. Liang, N. H. Attanayake, K. V. Greco, B. J. Neyhouse, J. L. Barton, A. P. Kaur, W. L. Eubanks, F. R. Brushett, J. Landon, and S. A. Odom, Comparison of Separators vs Membranes in Nonaqueous Redox Flow Battery Electrolytes Containing Small Molecule Active Materials, ACS Applied Energy Materials, 2021
97. B. J. Neyhouse, A. M. Fenton Jr., and F. R. Brushett, Too Much of a Good Thing? Assessing Performance Tradeoffs of Two-Electron Compounds for Redox Flow Batteries, Journal of the Electrochemical Society, 2021. 168(5), 050501
96. M. J. Orella, M. E. Leonard, Y. Román-Leshkov, and F. R. Brushett, High-throughput Analysis of Contact Angle Goniometry Data Using DropPy, SoftwareX, 2021. 14,100665
95. C. T. Wan, R. R. Jacquemond, Y.-M. Chiang, K. Nijmeijer, F. R. Brushett, and A. Forner-Cuenca, Non‐Solvent Induced Phase Separation Enables Designer Redox Flow Battery Electrodes, Advanced Materials, 2021. 2006716
94. S. Yadav, M. D. R. Kok, A. Forner-Cuenca, K. M. Tenny, Y.-M. Chiang, F. R. Brushett, R. Jervis, P. R. Shearing, D. Brett, E. P. L. Roberts, and J. T. Gostick, Fabrication of High Surface Area Ribbon Electrodes for Use in Redox Flow Batteries via Coaxial Electrospinning, Journal of Energy Storage, 2021 Journal of Energy Storage, 2021. 33, 102079
93. W. Gao, M. J. Orella, T. J. Carney, Y. Román-Leshkov, J. Drake, and F.R. Brushett, Understanding the Impact of Convective Transport on Intercalation Batteries Through Dimensional Analysis, Journal of the Electrochemical Society, 2020. 167(14), 140551
92. J. A. Kowalski, A. M. Fenton Jr., B. J. Neyhouse, and F. R. Brushett, A Method for Evaluating Soluble Redox Couple Stability Using Microelectrode Voltammetry, Journal of the Electrochemical Society, 2020. 167(16), 160513
91. M. E. Leonard, M. J. Orella, N. Aiello, Y. Román-Leshkov, A. Forner-Cuenca, and F. R. Brushett, Flooded by Success: On the Role of Electrode Wettability in CO2 Electrolyzers that Generate Liquid Products, Journal of the Electrochemical Society, 2020. 167(12), 124521
Editor’s Choice paper
90. M. Heydari Gharahcheshmeh, C. T. Wan, Y. Ashraf Gandomi, K. V. Greco, A. Forner-Cuenca, Y.-M. Chiang, F. R. Brushett, and K. K. Gleason, Ultrathin Conformal oCVD PEDOT Coatings on Carbon Electrodes Enable Improved Performance of Redox Flow Batteries, Advanced Materials Interfaces, 2020. 7(20), 2000855
89. Z. Cheng, K. M. Tenny, A. Pizzolato, A. Forner-Cuenca, V. Verda, Y.-M. Chiang, F. R. Brushett, and R. Behrou, Data-Driven Electrode Parameter Identification for Vanadium Redox Flow Batteries Through Experimental and Numerical Methods, Applied Energy, 2020. 279, 115530
88. B. Chakrabarti, E. Kalamaras, A. K. Singh, A. Bertei, J. Rubio-Garcia, V. Yufit, K. M. Tenny, B. Wu, F. Tariq, Y. S. Hajimolana, N. Brandon, J. Low, E. P.L. Roberts, Y.-M. Chiang, and F. R. Brushett, Modeling of redox flow battery electrode processes at a range of length scales: a review, Sustainable Energy & Fuels, 2020. 4, 5433-5468
87. L. Trahey, F. R. Brushett, N. P. Balsara, G. Ceder, L. Cheng, Y.-M. Chiang, N. T. Hahn, B. J. Ingram, S. D. Minteer, J. S. Moore, K. T. Mueller, L. F. Nazar, K. A. Persson, D. J. Siegel, K. Xu, K. R. Zavadil, V. Srinivasan, and G. W. Crabtree, Energy storage emerging: A perspective from the Joint Center for Energy Storage Research, PNAS, 2020. 117(23), 12550-12557
86. C. T. Wan, D. López Barreiro, A. Forner-Cuenca, J.-W. Barotta, M. Hawker, G. Han, H.-C. Loh, A. Masic, D. L. Kaplan, Y.-M. Chiang, F. R. Brushett, F. J. Martin-Martinez, and M. J. Buehler, Exploration of Biomass-Derived Activated Carbons for Use in Vanadium Redox Flow Batteries, ACS Sustainable Chem. Eng., 2020. 8(25), 9472-9482
85. K. E. Rodby, T. J. Carney, Y. Ashraf Gandomi, J. L. Barton, R. M. Darling, and F. R. Brushett, Assessing the levelized cost of vanadium redox flow batteries with capacity fade and rebalancing, Journal of Power Sources, 2020. 460, 227958
84. K. M. Tenny, A. Forner-Cuenca, Y.-M. Chiang, and F. R. Brushett, Comparing Physical and Electrochemical Properties of Different Weave Patterns for Carbon Cloth Electrodes in Redox Flow Batteries, Journal of Electrochemical Energy Conversion and Storage, 2020. 17(4), 041108
Invited contribution to the special issue “Emerging Investigators in Electrochemical Energy Conversion and Storage 2020”
83. F. R. Brushett, M. J. Aziz, and K. E. Rodby, On Lifetime and Cost of Redox-Active Organics for Aqueous Flow Batteries, ACS Energy Letters, 2020. 5(3), 879-884
82. J. A. Kowalski, T. J. Carney, J. Huang, L. Zhang, and F. R. Brushett, An investigation on the impact of halidization on substituted dimethoxybenzenes, Electrochimica Acta, 2020. 335, 135580
81. J. A. Kowalski, B. J. Neyhouse, and F. R. Brushett, The impact of bulk electrolysis cycling conditions on the perceived stability of redox active materials, Electrochemistry Communications, 2020. 111, 106625
80. D. Zhang, A. Forner-Cuenca, O. O. Taiwo, V. Yufit, F. R. Brushett, N. P. Brandon, S. Gu, and Q. Cai, Understanding the role of the porous electrode microstructure in redox flow battery performance using an experimentally validated 3D pore-scale lattice Boltzmann model, Journal of Power Sources, 2020. 447, 227249
79. M. J. Orella, S. M. Brown, M. E. Leonard, Y. Román-Leshkov, and F. R. Brushett, A General Techno‐Economic Model for Evaluating Emerging Electrolytic Processes, Energy Technology, 2019. 8(11), 1900994
78. A. Forner-Cuenca and F. R. Brushett, Engineering porous electrodes for next-generation redox flow batteries: recent progress and opportunities, Current Opinion in Electrochemistry, 2019. 18, 113-122
Invited contribution to the special issue “Energy Storage – Energy Transformation”
77. M. E. Leonard, L. E. Clarke, A. Forner-Cuenca, S. M. Brown, and F. R. Brushett, Investigating Electrode Flooding in a Flowing Electrolyte, Gas-Fed Carbon Dioxide Electrolyzer, ChemSusChem, 2019. 13(2), 400-411
Listed as a Very Important Paper in ChemSusChem
76. M. Orella, T. Z. H. Gani, J. V. Vermaas, M. L. Stone, E. M. Anderson, G. T. Beckham, F. R. Brushett, and Y. Román-Leshkov, Lignin-KMC: A Toolkit for Simulating Lignin Biosynthesis, ACS Sustainable Chem. Eng., 2019. 7(22), 18313-18322
75. M. Gigli, J. A. Kowalski, B. J. Neyhouse, A. D’Epifanio, F. R. Brushett, and S. Licoccia, Investigating the factors that influence resistance rise of PIM-1 membranes in nonaqueous electrolytes, Electrochemistry Communications, 2019. 107, 106530
74. S. Sen, S. M. Brown, M. Leonard, and F. R. Brushett, Electroreduction of carbon dioxide to formate at high current densities using tin and tin oxide gas diffusion electrodes, Journal of Applied Electrochemistry, 2019. 49(9), 917-928
73. T. Z. H. Gani, M. J. Orella, E. M. Anderson, M. L. Stone, F. R. Brushett, G. T. Beckham, and Y. Román-Leshkov, Computational evidence for kinetically controlled radical coupling during lignification, ACS Sustainable Chem. Eng., 2019. 7(15), 13270-13277
72. A. Forner-Cuenca, E. E. Penn, A. M. Oliveira, and F. R. Brushett, Exploring the Role of Electrode Microstructure on the Performance of Non-Aqueous Redox Flow Batteries, Journal of The Electrochemical Society, 2019. 166(10), A2230-A2241
71. J. L. Barton, A. I. Wixtrom, J. A. Kowalski, E. A. Qian, D. Jung, F. R. Brushett, and A. M. Spokoyny, Perfunctionalized Dodecaborate Clusters as Stable Metal-Free Active Materials for Charge Storage, ACS Appl. Energy Mater., 2019. 2(7), 4907-4913
70.C. Wiberg, T. J. Carney, F. Brushett, E. Ahlberg, and E. Wang, Dimerization of 9,10-anthraquinone-2,7-Disulfonic acid (AQDS), Electrochimica Acta, 2019. 317, 478-485
69. N. H. Attanayake, J. A. Kowalski, K. V. Greco, M. D. Casselman, J. D. Milshtein, S. J. Chapman, S. R. Parkin, F. R. Brushett, and S. A. Odom, Tailoring Two-Electron-Donating Phenothiazines To Enable High-Concentration Redox Electrolytes for Use in Nonaqueous Redox Flow Batteries, Chemistry of Materials, 2019. 31(12), 4353-4363
68. J. L. Barton and F. R. Brushett, A One-Dimensional Stack Model for Redox Flow Battery Analysis and Operation, Batteries, 2019. 5(1), 25
Invited contribution to the special issue “Vanadium Redox Flow Battery and Its Applications”
67. M. M. Machovina, E. S. Ellis, T. J. Carney, F. R. Brushett, and J. L. DuBois, How a cofactor-free protein environment lowers the barrier to O2 reactivity, J. Biol. Chem., 2019. 294(10), 3661-3669
66. K. V. Greco, A. Forner-Cuenca, A. Mularczyk, J. Eller, and F. R. Brushett, Elucidating the Nuanced Effects of Thermal Pretreatment on Carbon Paper Electrodes for Vanadium Redox Flow Batteries, ACS Appl. Mater. Interfaces, 2018. 10(51), 44430-44442
65. P. Bai, J. Guo, M. Wang, A. Kushima, L. Su, J. Li, F. R. Brushett, and M. Z. Bazant, Interactions between Lithium Growths and Nanoporous Ceramic Separators, Joule, 2018. 2(11), 2434-2449
64. T. J. Carney, D. S. Hodge, L. Trahey, and F. R. Brushett, The Joint Center for Energy Storage Research: A New Paradigm of Research, Development, and Demonstration Chapter 2 in Electrochemical Engineering: From Discovery to Product, 2018.
63. J. L. Barton, J. D. Milshtein, J. J. Hinricher, and F. R. Brushett, Quantifying the impact of viscosity on mass-transfer coefficients in redox flow batteries, Journal of Power Sources, 2018. 399, 133-143
62. V. Dieterich, J. Milshtein, J. Barton, T. Carney, R. Darling, and F. Brushett, Estimating the Cost of Organic Battery Active Materials: A Case Study on Anthraquinone Disulfonic Acid, Translational Materials Research, 2018. 5, 034001
61. M. J. Orella, Y. Román-Leshkov, and F. R. Brushett, Emerging opportunities for electrochemical processing to enable sustainable chemical manufacturing, Current Opinion in Chemical Engineering, 2018. 20, 159-167
2014-2017
60. S. Sen, M. Leonard, R. Radhakrishnan, S. Snyder, B. Skinn, D. Wang, T. Hall, E. J. Taylor, and F. R. Brushett, Pulse Plating of Copper onto Gas Diffusion Layers for the Electroreduction of Carbon Dioxide, MRS Advances, 2017. 3(23), 1277-1284
59. J. D. Milshtein, R. M. Darling, J. Drake, M. L. Perry, and F. R. Brushett, The Critical Role of Supporting Electrolyte Selection on Flow Battery Cost, Journal of The Electrochemical Society, 2017. 164(14), A3883-A3895
58. J. A. Kowalski, M. D. Casselman, A. P. Kaur, J. D. Milshtein, C. F. Elliott, S. Modekrutti, N. H. Attanayake, N. Zhang, S. R. Parkin, C. Risko, F. R. Brushett, and S. A. Odom, A Stable Two-Electron-Donating Phenothiazine for Application in Nonaqueous Redox Flow Batteries, Journal of Materials Chemistry A, 2017. 5, 24371-24379
57. Z. Li, M. S. Pan, L. Su, P.-C. Tsai, A. F. Badel, J. M. Valle, S. L. Eiler, K. Xiang, F. R. Brushett, and Y.-M. Chiang, Air-Breathing Aqueous Sulfur Flow Battery for Ultralow-Cost Long-Duration Electrical Storage, Joule, 2017, 1, 306-327
Featured as a “Joule” backstory and as the October 2017 cover art
56. E. V. Carino, D. J. Newman, J. G. Connell, C. Kim, and F. R. Brushett, Early Stage Anodic Instability of Glassy Carbon Electrodes in Propylene Carbonate Solvent Containing Lithium Hexafluorophosphate, Langmuir, 2017. 33(43), 11911–11918
55. L. Su, A. F. Badel, C. Cao, J. J. Hinricher, and F. R. Brushett, Toward an Inexpensive Aqueous Polysulfide-Polyiodide Redox Flow Battery, Industrial & Engineering Chemistry Research, 2017. 56(35), 9783–9792
Invited paper
I&EC Research special issue for the 2017 Class of Influential Researchers
54. J. D. Milshtein, J. L. Barton, T. J. Carney, J. A. Kowalski, R. M. Darling, and F. R. Brushett, Towards Low Resistance Nonaqueous Redox Flow Batteries, Journal of The Electrochemical Society, 2017. 164(12), A2487-A2499
53. S. Liu, M. Kok, Y. Kim, J. L. Barton, F. R. Brushett, and J. Gostick, Evaluation of Electrospun Fibrous Mats Targeted for Use as Flow Battery Electrodes, Journal of The Electrochemical Society, 2017. 164(9), A2038-A2048
52. J. D. Milshtein, K. M. Tenny, J. L. Barton, J. Drake, R. M. Darling, and F. R. Brushett, Quantifying Mass Transfer Rates in Redox Flow Batteries, Journal of The Electrochemical Society, 2017. 164(11), E3265-E3275
JES Focus Issue on Mathematical Modeling of Electrochemical Systems at Multiple Scales in Honor of John Newman
One of the most downloaded in Q1 & Q2 2018!
51. L. Su, M. Ferrandon, J. L. Barton, N. Upia de la Rosa, J. T. Vaughey, and F. R. Brushett, An investigation of 2,5-di-tertbutyl-1,4-bis(methoxyethoxy)benzene in ether-based electrolytes, Electrochimica Acta, 2017. 246, 251-258
50. B. Yan, N. M. Concannon, J. D. Milshtein, F. R. Brushett, and Y. Surendranath, A Membrane-Free Neutral pH Formate Fuel Cell Enabled by a Selective Nickel Sulfide Oxygen Reduction Catalyst, Angewandte Chemie International Edition, 2017. 56(26), 7496-7499
Listed as a Very Important Paper in Angewandte Chemie International Edition
49. T. J. Carney, S. J. Collins, J. S. Moore, and F. R. Brushett, Concentration-Dependent Dimerization of Anthraquinone Disulfonic Acid and Its Impact on Charge Storage, Chemistry of Materials, 2017. 29(11), 4801-4810
48. W. Duan, J. Huang, J. A. Kowalski, I. A. Shkrob, M. Vijayakumar, E. Walter, B. Pan, Z. Yang, J. D. Milshtein, B. Li, C. Liao, Z. Zhang, W. Wang, J. Liu, J. S. Moore, F. R. Brushett, L. Zhang, and X. Wei, “Wine-Dark Sea” in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability, ACS Energy Letters, 2017. 2, 1156-1161
47. D. D. Nevers, F. R. Brushett, and D. R. Wheeler, Engineering radical polymer electrodes for electrochemical energy storage, Journal of Power Sources, 2017. 352, 226-244
46. T. Salih, S. M. Brown, C. Kim, K. Carroll, F. R. Brushett, and A. Bumajdad, Cost Effective and Scalable Synthesis of Supported Au Nanoparticles for the Electroreduction of CO2 to CO, Science of Advanced Materials, 2017. 9(6), 888-895
45. J. D. Milshtein, S. L. Fisher, T. M. Breault, L. T. Thompson, and F. R. Brushett, Feasibility of a supporting salt free non-aqueous redox flow battery utilizing ionic active materials, ChemSusChem, 2017. 10, 2080-2088
44. S. Sen, B. Skinn, T. Hall, M. Inman, E. J. Taylor, and F. R. Brushett, Pulsed Electrodeposition of Tin Electrocatalysts onto Gas Diffusion Layers for Carbon Dioxide Reduction to Formate, MRS Advances, 2017. 2(8), 451-458
43. J. D. Milshtein, A. P. Kaur, M. D. Casselman, J. A. Kowalski, S. Modekrutti, P. Zhang, N. H. Attanayake, C. F. Elliott, S. R. Parkin, C. Risko, F. R. Brushett, and S. A. Odom, High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries, Energy & Environmental Science, 2016. 9, 3531-3543
42. R. Dmello, J. D. Milshtein, F. R. Brushett, and K. C. Smith, Cost-Driven Materials Selection Criteria for Redox Flow Battery Electrolytes, Journal of Power Sources, 2016. 330, 261-272
41. P. Bai, J. Li, F. R. Brushett, and M. Z. Bazant, Transition of lithium growth mechanisms in liquid electrolytes, Energy & Environmental Science, 2016. 9, 3221-3229
40. J. A. Kowalski, L. Su, J. D. Milshtein, and F. R. Brushett, Recent advances in molecular engineering of redox active organic molecules for nonaqueous flow batteries, Current Opinion in Chemical Engineering, 2016. 13, 45-52
Invited Review
39. J. Huang, B. Pan, W. Duan, X. Wei, R. S. Assary, L. Su, F. R. Brushett, L. Cheng, C. Liao, M. S. Ferrandon, W. Wang, Z. Zhang, A. K. Burrell, L. A. Curtiss, I. A. Shkrob, J. S. Moore, and L. Zhang, The lightest organic radical cation for charge storage in redox flow batteries, Scientific Reports, 2016. 6, 32102
38. S. Burlatsky, R. M. Darling, D. Novikov, V. V. Atrazhev, V. I. Sultanov, T. Y. Astakhova, L. Su, and F. R. Brushett, Molecular Dynamics Modeling of the Conductivity of Lithiated Nafion Containing Nonaqueous Solvents, Journal of The Electrochemical Society, 2016. 163, A2232-A2239
37. S. M. Laramie, J. D. Milshtein, T. M. Breault, F. R. Brushett, and L. T. Thompson, Performance and cost characteristics of multi-electron transfer common ion exchange non-aqueous redox flow batteries, Journal of Power Sources, 2016. 327, 681-692
36. J. D. Milshtein, J. L. Barton, R. M. Darling, and F. R. Brushett, 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl as a model organic redox active compound for nonaqueous flow batteries, Journal of Power Sources, 2016. 327, 151-159
35. K. Carroll, T. Burger, L. Langenegger, S. Chavez, S. T. Hunt, Y. Roman-Leshkov, and F. R. Brushett, Electrocatalytic Hydrogenation of Oxygenates using Earth-Abundant Transition-Metal Nanoparticles under Mild Conditions, ChemSusChem, 2016. 9, 1904-1910
34. J. Han, M. Wang, P. Bai, F. R. Brushett, and M. Z. Bazant, Dendrite Suppression by Shock Electrodeposition in Charged Porous Media, Scientific Reports, 2016. 6, 28054
33. E. Chenard, A. Sustrino, L. Zhu, R. S. Assary, J. A. Kowalski, J. L. Barton, J. A. Bertke, D. L. Gray, F. R. Brushett, L. A. Curtiss, and J. S. Moore, Synthesis of Pyridine- and Pyrazine-BF3 Complexes and Their Characterization in Solution and Solid State, Journal of Physical Chemistry C, 2016. 120, 8461-8471
32. E. V. Carino, J. Staszak-Jirkovsky, R. S. Assary, L. A. Curtiss, N. M. Markovic, and F. R. Brushett, Tuning the Stability of Organic Active Materials for Nonaqueous Redox Flow Batteries via Reversible, Electrochemically Mediated Li+ Coordination, Chemistry of Materials, 2016. 28, 2529-2539
31. W. Duan, R. S. Vemuri, J. D. Milshtein, S. Laramie, R. D. Dmello, J. Huang, D. Hu, M. Vijayakumar, W. Wang, J. Liu, R. M. Darling, L. Thompson, K. Smith, J. S. Moore, F. R. Brushett, and X. Wei, A symmetric organic-based nonaqueous redox flow battery and its state of charge diagnostics by FTIR, Journal of Materials Chemistry A, 2016. 4, 5448-5456
Included in the themed collection: 2016 Journal of Materials Chemistry A HOT Papers
30. L. Su, R. M. Darling, K. G. Gallagher, W. Xie, J. L. Thelen, A. F. Badel, J. L. Barton, K. J. Cheng, N. P. Balsara, J. S. Moore and F. R. Brushett, An Investigation of the Ionic Conductivity and Species Crossover of Lithiated Nafion 117 in Nonaqueous Electrolytes, Journal of The Electrochemical Society, 2016. 163(1), A5253-A5262
JES Focus Issue on Redox Flow Batteries–Reversible Fuel Cells
29. R. M. Darling, K. G. Gallagher, W. Xie, L. Su, and F. R. Brushett, Transport Property Requirements for Flow Battery Separators, Journal of The Electrochemical Society, 2016. 163(1), A5029-A5040
JES Focus Issue on Redox Flow Batteries–Reversible Fuel Cells
28. J. D. Milshtein, L. Su, C. Liou, A. F. Badel, and F. R. Brushett, Voltammetry study of quinoxaline in aqueous electrolytes, Electrochimica Acta, 2015. 180, 695-704
27.F. R. Brushett, A. N. Jansen, J. T. Vaughey, L. Su, J. D. Milshtein, Materials for use with aqueous redox flow batteries and related methods and systems, Massachusetts Institute of Technology & UChicago, Argonne LLC, assignees. Patents US 2015/0236543
A1 & WO 2015/126907 A1.
August 20, 2015
26. J. Huang, L. Su, J. A. Kowalski, J. L. Barton, M. Ferrandon, A. K. Burrell, F. R. Brushett and L. Zhang, A subtractive approach to molecular engineering of dimethoxybenzene-based redox materials for non aqueous flow batteries, Journal of Materials Chemistry A, 2015. 3, 14971-14976
25. L. Su, J. A. Kowalski, K. J. Carroll and F. R. Brushett, Recent Developments and Trends in Redox Flow Batteries, Chapter in Rechargeable Batteries: Materials, Technologies and New Trends, 2015.
24. A. S. Sakti, R. A. Miller, and F. R. Brushett, Energy Storage Systems for the Electric Power Sector, Appendix C in The Future of Solar Energy: An Interdisciplinary MIT Study, 2015.
23. E. V. Carino, C. E. Diesendruck, J. S. Moore, L. A. Curtiss, R. S. Assary, and F. R. Brushett, BF3-promoted electrochemical properties of quinoxaline in propylene carbonate, Royal Society of Chemistry Advances, 2015. 5(24), 18822-18831
22. R. Darling, K. G. Gallagher, J. A. Kowalski, S. Ha, and F. R. Brushett, Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries, Energy & Environmental Science, 2014. 7, 3459-3477
21. L. Su, M. Ferrandon, J. A. Kowalski, J. T. Vaughey, and F. R. Brushett, Electrolyte Development for Non-Aqueous Redox Flow Batteries Using a High-Throughput Screening Platform, Journal of The Electrochemical Society, 2014. 161(12), A1905-A1914
20. R. S. Assary, F. R. Brushett, and L. A. Curtiss, Reduction potential predictions of some aromatic nitrogen-containing molecules, Royal Society of Chemistry Advances, 2014. 4, 57442-57451
19. F. R. Brushett, L. Trahey, X. Xiao, and J. T. Vaughey, Full-Field Synchrotron Tomography of Nongraphitic Foam and Laminate Anodes for Lithium-Ion Batteries, ACS Applied Materials & Interfaces, 2014. 6, 4524–4534
2006-2013 (pre-MIT)
18. M. S, Naughton, C. E. Tornow, Y. Bonita, H. R. M. Jhong, F. R. Brushett, A. A. Gewirth, and P. J. A. Kenis, In-situ measurement of ethanol tolerance in an operating fuel cell, International Journal of Hydrogen Energy, 2013. 38, 8980-8991
17. H. R. M. Jhong, F. R. Brushett, and P. J. A. Kenis, The Effects of Catalyst Layer Deposition Methodology on Electrode Performance, Advanced Energy Materials, 2013. 3, 589-599
Front cover of the Advanced Energy Materials Vol. 3 No. 5 on 5/201
16. F. R. Brushett, J. T. Vaughey, and A. N. Jansen, An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery, Advanced Energy Materials, 2012. 2, 1390-1396
15. M. R. Thorson, F. R. Brushett, C. J. Timberg, and P. J. A. Kenis, Design rules for electrode arrangement in an air-breathing alkaline direct methanol laminar flow fuel cell. Journal of Power Sources, 2012. 218, 28-33
14. F. R. Brushett, M. S. Naughton, J. W. D. Ng, L. L. Yin, and P. J. A. Kenis, Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell, International Journal of Hydrogen Energy, 2012. 37, 2559-2570
13. H. R. M. Jhong, F. R. Brushett, L. L. Yin, D. Stevenson, and P. J. A. Kenis, Combining Structural and Electrochemical Analysis of Electrodes using Micro-Computed Tomography and a Microfluidic Fuel Cell, Journal of The Electrochemical Society, 2012.159, B292-B298
Highlighted in: Tech Highlights in ECS Interface Summer Edition
12. P. O. Lopez-Montesinos, N. Yossakda, A. Schmidt, F. R. Brushett, W. Pelton, and P. J. A. Kenis, Design, fabrication, and characterization of a planar, silicon-based, monolithically integrated micro laminar flow fuel cell with a bridge-shaped microchannel cross-section, Journal of Power Sources, 2011. 196, 4638-4645
11. M. S. Naughton, F. R. Brushett, and P. J. A. Kenis, Carbonate resilience of flowing electrolyte-based alkaline fuel cells, Journal of Power Sources, 2011. 191, 1762-1768
10. F. R. Brushett, M. S. Thorum, N. S. Lioutas, M. S. Naughton, C. Tornow, H. R. M. Jhong, A. A. Gewirth, and P. J. A. Kenis, A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications, Journal of The American Chemical Society, 2010. 132(35), 12185-12187
9. F. R. Brushett, H. T. Duong, J. W. D. Ng, R. L. Behrens, A. Wieckowski, and P. J. A. Kenis, Investigation of Pt, Pt3Co and Pt3Co/Mo cathodes for the ORR in a Microfluidic H2/O2 Fuel Cell, Journal of The Electrochemical Society, 2010. 157, B837-B845
8. S. K. Yoon, R. S. Jayashree, F. R. Brushett, P. O. Lopez-Montesinos, D. Natarajan, L. J. Markoski, and P. J. A. Kenis, On the Performance of Membraneless Laminar Flow-Based Fuel Cells, Journal of Power Sources, 2010. 195, 3569-3578
7. F. R. Brushett, R. S. Jayashree, W. P. Zhou, and P. J. A. Kenis, Investigation of Fuel and Media Flexible Laminar Flow-Based Fuel Cells, Electrochimica Acta, 2009. 54, 7099-7105
6. A. S. Hollinger, F. R. Brushett, L. J. Markoski, and P. J. A. Kenis, Scaling and Manufacturing of Laminar Flow-Based Fuel Cells. Proceedings of MicroTAS Conference, Groningen, Netherlands, 2010. 1748-1750
5. F. R. Brushett, P. J. A. Kenis, and A. Wieckowski, New Concepts in the Chemistry and Engineering of Low-Temperature Fuel Cells, Fuel Cell Science: Theory, Fundamentals, and Bio-catalysis, A. Wieckowski & J.K. Norskov, editors, (John Wiley & Sons, Inc.), 2010. 565-610
4. F. R. Brushett, W. P. Zhou, R. S. Jayashree, and P. J. A. Kenis, Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform, Journal of The Electrochemical Society, 2009. 156, B565-B571
3. F. R. Brushett, A. S. Hollinger, L. J. Markoski, and P. J. A. Kenis, Microfluidic Fuel Cells as Microscale Power Sources and Analytical Platforms, Proceedings of ASME 2009 2nd Micro/Nanoscale Heat & Mass Transfer International Conference, Shanghai, China
2. F. R. Brushett, M. Mitchell, R. S. Jayashree, W. P. Zhou, and P. J. A. Kenis, Vapor Feed Direct Methanol Fuel Cell with Flowing Electrolyte, ECS Transactions, 2007. 11, 1419-1424
1. F. A. Ngantung, P. G. Miller, F. R. Brushett, G. L. Tang, and D. I. C. Wang, RNA Interference of Sialidase Improves Glycoprotein Sialic Acid Content Consistency, Biotechnology and Bioengineering, 2006. 95, 106-119